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Properties and Hazards of LPG

Properties

LPG is liquefied petroleum gas and is:

  • Obtained during the processing of crude oil, or direct from the North Sea.
  • Colourless and odourless. An odourising agent is added before distribution to give its characteristic smell.
  • Half as heavy as water when in liquid form. It will float on water before vapourising.
  • Easily liquefied by pressure, taking up only around 1/250th of its gaseous volume. This means that a large amount of LPG can be stored in a small place.
  • Either commercial butane or commercial propane. These are similar in use but propane has a boiling point and hence a higher storage pressure. Commercial propane is predominantly an outdoor fuel.

At ambient temperature (i.e. 15 degrees Celcius), propane and butane bottles contain the following pressures:

Commercial BUTANE
2BAR (28psig)
Commercial PROPANE
7BAR(100psig)

Hazards

LPG:

  • LPG is approximately twice as heavy as air when in gas form and will tend to sink to the lowest possible level and may accumulate in cellars, pits, drains etc.
  • LPG in liquid form can cause severe cold burns to the skin owing to its rapid vapourisation.
  • Vapourisation can cool equipment so that it may be cold enough to cause cold burns.
  • LPG forms a flammable mixture with air in concentrations of between 2% and 10%.
  • It can, therefore, be a fire and explosion hazard if stored or used incorrectly.
  • Vapour/air mixtures arising from leakages may be ignited some distance from the point of escape and the flame can travel back to the source of the leak.
  • At very high concentrations vapour can have an anaesthetic effect and subsequently become an asphyxiant by diluting the available oxygen.
  • A cylinder that has contained LPG is normally empty but may still contain LPG vapour and be potentially dangerous. Therefore treat all LPG cylinders as if they were full.